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Two accidental reactions reveal complementary light-driven routes to alkenes

Chemistry World reports a Science editor connected the teams after rejecting their papers and spotting similarities.

Chemistry WorldCW
1 Source, 33m ago, first seen 33m ago

TLDR

Chemistry World reports that teams in the US and Germany independently discovered ways to use visible light to turn nitroalkanes into substituted alkenes. The US team’s method needs no catalyst and mainly produces tri-substituted alkenes; the German team’s ruthenium-catalyzed method primarily produces tetra-substituted ones. The teams are now collaborating to refine the reactions.

Combined views

309

1 Source, first seen 33m ago

Combined views

309

1 Source, first seen 33m ago

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1 Source

Chemistry World@ChemistryWorld‘It’s not an obvious retrosynthetic disconnection. Nitroalkanes to form a double bond, it’s not the first thing people think of, right? That brings some excitement,’ says Marvin Parasram. @nyuniversity @uni_regensburg @J_A_C_S @RoySocChem #photochemistry https://www.chemistryworld.com/news/two-accidental-nitroalkane-reactions-reveal-complementary-photochemical-routes-to-alkenes-and-unite-their-discoverers/4024314.article?utm_campaign=organic_social&utm_medium=social&utm_source=twitter1h
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    1 Source

    Chemistry World@ChemistryWorld‘It’s not an obvious retrosynthetic disconnection. Nitroalkanes to form a double bond, it’s not the first thing people think of, right? That brings some excitement,’ says Marvin Parasram. @nyuniversity @uni_regensburg @J_A_C_S @RoySocChem #photochemistry https://www.chemistryworld.com/news/two-accidental-nitroalkane-reactions-reveal-complementary-photochemical-routes-to-alkenes-and-unite-their-discoverers/4024314.article?utm_campaign=organic_social&utm_medium=social&utm_source=twitter1h
    Today's Rank

    #16

    Today's Rank

    #16